Chemical constituents of clove

Three essential oils are available from clove species. Eugenol is one of the main compounds found in cloves. Bioactive compounds present in clove bud oil are volatile in nature at room temperatures dorman and deans, 2000. Constituents were then identified by comparing the results of the chromatogram and reference retention time using wiley mass spectra library wiley w9n11. These compounds are volatile and organic, meaning they quickly evaporate and their structure is primarily composed of carbon atoms. Hydrodistillation process was running for 24 hours. Clove syzygium aromaticum plant profiler sigmaaldrich.

Volatile composition and antioxidant properties of clove. The primary component of clove is eugenol that adds up to 70 to 90% of the clove essential oil constituent. Clove oil is a colourless or pale yellow, thin, oily liquid when freshly prepared. It also has been used topically as a counterirritant. A dept experiment several flavonoids via solvent extraction, showed the presence of four methyl groups, chemical constituents of clove syzygium aromaticum, fam. The main constituents of the essential oil are phenylpropanoids such as carvacrol, thymol. Chemical constituents of clove oil bud essential oil. Many plant species have been reported to have pharmacological activities attributable to their phytoconstituents such are glycosides, saponins, flavonoids, steroids, tannins, alkaloids, terpenes, etc. Each bottle of essential oil contains a unique blend of chemical constituents. There is a concern that taking clove oil might cause bleeding in people with bleeding disorders. Clove oil guide benefits, properties, characteristics.

Clove bud oil, the most expensive and the best quality product, contains eugenol 8090%, eugenol acetate 15%, and beta caryophyllene 512%. Mar, 2014 click to enlarge now available to purchase as herbspice jar labels here. Garlic contains at least 33 sulfur compounds like aliin, allicin, ajoene, allylpropl, diallyl, trisulfide, sallylcysteine, vinyldithiines, sallylmercaptocystein, and others. A considerable limitation of the evidence base is the lack of information on the chemical composition of clove samples used for both in vitro and in vivo investigations. This plant represents one of the richest source of phenolic compounds such as eugenol, eugenol acetate and gallic acid and. The single seed present in the fruit contains starch, which is absent in clove bud. The major chemical ingredients of the oils were eugenol, i.

So, from these chemical constituents it is clear that clove buds essential oil of bangladesh has medicinal properties because of the medicinal characteristics of these constituents. Cloves are the dried aromatic flower buds from an evergreen tree native to. In general, pure essential oils can be subdivided into two distinct groups of chemical constituents. The composition, structure, sources, and applications of. Mar 23, 2007 the essential oil extracted from the dried flower buds of clove, eugenia caryophyllata l.

Clove oil contains a chemical called eugenol that seems to slow blood clotting. It also contains vanillin, 10 to percent of tannin, terpenic acid, gum. Chemical components of the essential oil from the buds and leaves of other species and variant of syzygium had been reported by several workers 15 17. More minor constituents are also contributors to the characteristic odour, for example compounds such as methylamylketone and methylsalicylate. The essential oils of ocimum americanum, with the exception of clove basil, were rich in phenylpropanoids and a single biosynthetic origin is indicated for. Herbal medicinal products have been documented as a significant source for discovering new pharmaceutical molecules that have been used to treat serious diseases. Chemical constituents of clove flower clove contains 15 to 20 percent of volatile oil, the chief constituent of which is eugenol. The objective of this research is to determine significant differences of constituents in terms of. The essential oil from clove demonstrated scavenging activity against the 2,2diphenyl1picryl hydracyl dpph radical at concentrations lower than the concentrations of eugenol, butylated hydroxytoluene. Table 1 represents the chemical composition of the essential oil from the bud of clove syzygium aromaticum. We sell clove leaf oil, which is extracted by water distillation, containing the desired lower percentage of eugenol. Other known constituents of clove oils are eugenyl acetate, methyl alcohol, methyl salicylate, furfurol, pinene, vanillin and. Mother cloves anthophylli are the ripe fruits of cloves that are ovoid, brown berries, unilocular and oneseeded. The chemical composition and biological activity of clove essential.

It possesses a strong, fragrant, spicy odour and a pungent aromatic taste. It also contains small quantities of dimethyl furfural caryophyllene, aceteugenol, methylfurfural, and methyl salicylate. The oil has been used as an expectorant and antiemetic with inconsistent clinical results. Here mature clove flowers without corolla and stamens are also admixed. Monoterpenes and sesquiterpenes are the most common types of constituents found in essential oils. The main chemical components of clove oil are eugenol, eugenol acetate, isoeugenol and caryophyllene. This plant plays a vital role as a spice, but its essential oils and other constituents also have important activities, including antimicrobial 17 20, antifungal 21, antioxidant. Most of the chemical ingredients isolated and identified in the essential oil were mono and sesquiterpene, normal and cyclic hydrocarbons, phenolic. Other important essential oil constituents of clove oil include acetyl eugenol, betacaryophyllene, vanillin, crategolic acid, tannins such as bicornin, gallotannic acid, methyl salicylate painkiller, the flavonoids eugenin, kaempferol, rhamnetin, and eugenitin, triterpenoids such as oleanolic acid, stigmasterol, and campesterol and several. It is miscible with alcohol, ether and glacial acetic acid. Each has different chemical composition and flavour.

Clove oil is a very potent oil and should be used with care. Nov 09, 2018 clove can affect bloodclotting and may increase your risk of bleeding. Clove oil is used for diarrhea, hernia, and bad breath. Chemical composition and antibacterial effects of clove. Terpenes, organic compounds consisting of multiples of isoprene units containing five carbon atoms, are by far the most dominant constituents of essential oils. These also contain clove oil but only around 3 to 5% and hence considered as an adulterant. Clove oil contains a chemical called eugenol that may help to decrease pain and fight infections, but more research is needed. Garlic contains at least 33 sulfur compounds like aliin, allicin, ajoene, allylpropl, diallyl, trisulfide, sallylcysteine, vinyldithiines, s. As can be seen from this table, 18 compounds, representing about 99. Alphahumulene, benzoates 25, eugenol 4alil2metoxiphenol, eugenol acetate 5,14,10, ethyl acetate 8, beta caryophyllene, isoeugenol, phenylpropanoids 8, dehydrodieugenol 8, methyleugenol, methyl salicylate, transconiferyl aldehyde 8, and triterpenes oleanolic acid 9 are constituents of clove. With regard to the chemical compositions obtained of garlic, it can be concluded that sulfuric compositions are among active and applicable elements in garlic and allicin is one important sulfuric composition in garlic. Pdf chemical constituents of clove syzygium aromaticum. Gcms analysis of clove syzygium aromaticum bud essential.

Clove side effects, dosage, interactions drugs everyday. We sell clove oil, which is extracted by water distillation, containing the desired lower percentage of eugenol. The compound eugenol is responsible for most of the characteristic aroma of cloves. Pdf chemical constituents of clove syzygium aromaticum, f am. Clove essential oils have been analyzed by gcms 11. Different parts of the plant are used of many illnesses like cough, influenza. Jul 03, 2019 clove has a long history of culinary and medicinal use. Constituent definition is a member of a constituency. Oil of clove, also known as clove oil, is an essential oil extracted from the clove plant, syzygium aromaticum. Clove and clove oil are used for intestinal gas, nausea, and vomiting clove is applied directly to the gums used topically for toothache, for. Cloves are the immature unopened flower buds of the evergreen tree eugenia caryophyllus, which belongs to the myrtaceae family. Clove is native of indonesia but nowadays is cultured in several parts of the world including brazil in the state of bahia. Thirtysix and thirtyfour chemical constituents were identified based on gc. This essential oil comprises in total 23 identified constituents, among them eugenol 76.

Chaieb k1, hajlaoui h, zmantar t, kahlanakbi ab, rouabhia m, mahdouani k, bakhrouf a. Bud, leaf and stem essential oil composition of clove. The active properties of garlic depend on a pungent, volatile, essential oil. Great variability in the chemical compositions of the three essential oils was observed.

Pdf chemical composition and content of essential oil. Spices as clove, oregano, mint, thyme and cinnamon, have been employed for centuries as food preservatives and as medicinal. Chemical composition and antioxidant properties of clove leaf. Quantitative determination of nutritional and anti. Clove leaf and the essential oil extracted from these magical leaves is a powerful natural remedy for assisting proper digestion. It becomes darker and thicker on age or on exposure to air. The essential oil composition was identified by gas chromatography mass spectrometry gcms technique and also showed their medicinal properties according to the characteristics of the constituents present in the essential oil. Use of the oil in dentistry as an analgesic and local antiseptic continues today. Other major components are beta caryophyllene, methyl salicylate, kaempferol, acetyl eugenol, triterpenoids, gallotannic acid, rhamnetin, vanillin and eugenin. Clove is often found in the aromatherapy section of health food stores, and is used in the flavoring of some medicines. If you need surgery, dental work, or a medical procedure, stop taking clove at least 2 weeks ahead of time. Clove oil extraction methods, process guide agri farming.

This research enables the clarification of the role of clove products in culinary, food industry and in dieting respecting chemical composition and properties. People use the oils, dried flower buds, leaves, and stems to make medicine. Frac clove leaf essential oil eugenia carophyl tionation of the methylene chloride extract lus and the main constituent eugenol was of the buds on silica gel and. The biological activity of eugenia caryophyllata has been investigated on several microorganisms and parasites, including pathogenic bacteria, herpes simplex and. Eugenol is the component which is most responsible for clove aroma and comprises 7290% of the essential oil extracted from cloves 2. Constituent definition of constituent by merriamwebster. Clove essential oil uses and benefits for health everphi.

I thought itd be fun to take that a little further, and look at the major organic compounds present in various different herbs and spices that are frequently used in cooking, so thats what this poster tries to do. Cloves are green or pink when they are picked, and need to be dried until they become brown before they can be. E caryophyllene, i humulene and acetyl eugenol and several minor chemical ingredients were also obtained from the same clove oils. Chemical constituents of clove syzygium aromaticum, fam. The chemical composition and biological activity of clove. If in powdered form, excess of clove stalk can be made out by the presence of calcium oxalate prism and large thick walled stone cells which however are absent in official clove powder. In this research, we investigate the chemical compositions in garlic and also the process of producing allicin inside garlic. Clove essential oil ceo is traditionally used in the treatment of burns and wounds, and as a pain reliever in dental care as well as treating. The chemical composition and biological activity of clove essential oil, eugenia caryophyllata syzigium aromaticum l. Clove is most commonly applied directly to the gums for toothache, pain control during dental work, and other dentalrelated issues. Noori1 1chemistry department, college of sciences, university of baghdad, baghdad, iraq 2chemistry department, college of sciences, university of kufa, iraq corresponding author. Sep 12, 2018 the main constituents of clove essential oil are.

Clove is used for upset stomach and as an expectorant. Thus allyl sulfides are characteristics of oil of garlic. Chaieb k 1, hajlaoui h, zmantar t, kahlanakbi ab, rouabhia m, mahdouani k, bakhrouf a. Sulfurcontaining compounds such as alliin, allicin, ajoenes, vinyldithiins, and sul. Effect of crushing of clove bud syzygium aromaticum and.

The principal constituents of distilled clove bud oil 60% to 90% are the phenylpropanoids, including primarily eugenol 4allyl2methoxyphenol and carvacrol, thymol, and cinnamaldehyde. The effective role of clove in the inhibition of different degenerative diseases is attributed to the presence of various chemical constituents in high concentrations with antioxidant activity 10,11. Clove syzygium aromaticum is one of the most valuable spices that has been used for centuries as food preservative and for many medicinal purposes. Chemical constituents of clove leaf oil essential oil. The chemical composition of dried clove bud in bangladesh was investigated. It is ripe fruit of clove containing a single seed, unilocular. The clove bud essential oil 45 samples, leaf essential oil 32 samples and stem essential oil 44 samples of were analyz s. Chemical constituents and pharmacological action of ocimum sanctum indian holy basiltulsi sunita verma abstract oscimum sanctum commonly known as tulsi, belong to lamiaceae family. These cloves are distinctly larger 2025 mm 1017 mm, ovate and taper below. Using a simple micro chemical test for starch, the adulterant can be detected.

The main constituents of the essential oil are phenylpropanoids such as carvacrol, thymol, eugenol and cinnamaldehyde. The oil also contains approximately 10% acetyleugenol and small quantities of gallic acid, sesquiterpenes, furfural, vanillin, and methylnamyl ketone. Chemical constituents of syzygium aromaticum springerlink. The major chemical components of clove oil are eugenol, eugenol acetate, isoeugenol, and caryophyllene.

The antioxidant activity of a commercial rectified clove leaf essential oil eugenia caryophyllus and its main constituent eugenol was tested. Uses, side effects, interactions, dosage, and warning. Chemical components and therapeutic properties of clove essential oil. It consists of 9095% eugenol, and some other minor constituents. Clove oil can be extracted from the plant leaves, stem, and buds. Clove oil is obtained from distillation of the flowers, stems, and leaves of the clove tree eugenia aromatica. Chemical composition and antioxidant properties of clove. Clove oil is used in dental care and it can relieve toothache temporarily. Essential oil composition from twelve varieties of basil.

Its often stated that cooking is much like chemistry, or vice versa. The most important constituents of clove is the phenylpropene eugenol which gives this spice. Clove stalks are slender stems of the inflorescence axis that show opposite decussate branching. Clove is a plant grown in parts of asia and south america. Kamel chaieb, hafedh hajlaoui, tarek zmantar, amel ben kahlanakbi, mahmoud rouabhia, kacem mahdouani and amina bakhrouf, 2007. Chemical constituents of clove syzygium aromaticum, f am. Chemical structure, quality indices and bioactivity of. Clove oil syzygium aromaticum information on the origin. In addition, in vivo benefits of clove, clove oil, extracts of clove, and individual constituents toward established biomarkers of chronic disease need to be conducted using. Chemical composition of clove bud oil and development of.

Unfortunately, scientific research and publications about flavor in clove from indonesias origin are still limited. It has the cas number 8000348 clove is often found in the aromatherapy section of health food stores, and is used in the flavoring of some medicines. These are similar in colour to clove and contain less amount of volatile oil than clove 20. Chemical structure, quality indices and bioactivity of essential oil constituents, active ingredients from aromatic and medicinal plants, hany a. Being an effective carminative and anthelmintic, clove leaf oil has the power to enhance the secretion of hydrochloric acid in the stomach and support bowel movements along with peristalsis.

In this study, clove bud oil, which was cultivated in the mediterranean region of turkey, was provided from a private essential oil company in turkey. Bioactive chemical constituents, pharmacological and toxicological activities. Essential oil chemical constituents doterra essential oils. Secondly, only after the raw sumac, the ground clove has the amazing orac value of 290. Comparison of chemical constituents and antimicrobial. A major component of clove taste is imparted by the chemical eugenol. Individual oils, however, may contain appreciable quantities of straight chain, aromatic, or heterocyclic compounds. Chemical composition and antibacterial effects of clove syzygium aromaticum flowers khalid abdul kreem mohammed1, h.

Chemical composition and phytotoxic activity of clove. Essential oil chemical constituents in general, pure. Pharmacologically, clove has been documented as the main source of phenolic molecules like hidroxibenzoic acids, flavonoids, hidroxiphenyl propens, hidroxicinamic acids, and eugenol c 10 h 12 o 2which is the major bioactive moleculeand gallic acid derivatives like hidrolizable tannins that are found in high amounts in the fresh plant table 1 6,9,16. The chief chemical constituent of clove oil is eugenol about 85 percent. Ten constituents were identified andquantified, as shown in t able 1. Determining the chemical compositions of garlic plant and. Three different clove oils bud, leaves and stem differ in their composition. Externally, they are brownish, rough, and irregularly wrinkled longitudinally with short fracture and dry, woody texture. Review article chemical constituents and pharmacological. Clove essential oil is a derivative extracted by steam distillation from the dried flower buds of clove, eugenia caryophyllata l. The largest clove production contributors in indonesia are mostly coming from java and manado. In the course of continuous research on the chemical constituents of clove, four compounds 14 were obtained by phytochemical methods and their structures elucidated by modern spectroscopic techniques including 1 h nmr, c nmr broad band and dept, hmbc, hsqc, 1 h 1 h cosy, and 1 h 1 h noesy and comparison with the reported.